IB Chemistry Topic 2 & 12 Definitions

This page contains our IB Chemistry definitions for topic 2 & 12. By learning each one of these definitions, you will fully cover the content for IB Chemistry 'Models of Bonding & Structure'.
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adduct

Two molecules bound together by a dative bond

allotrope

A crystalline form of a compound

alloy

Metallic compounds (two metals mixed) that alter the properties of the components due to distortions in the lattice

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anabolic reaction

A reaction that bonds monomers together to form a macromolecule

anion

Non-metals that gain valence electrons to gain a negative charge

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catabolic reaction

A reaction that breaks a macromolecule down into monomers

cation

Positive ions. Commonly metals that lose valence electrons to gain a positive charge.

Conductivity

Ability of a material to conduct electricity 

coordinate covalent bond

A covalent bond formed when a single atom donates a shared pair of electrons. Also called dative covalent bond 

covalent bond

The electrostatic attraction of two nuclei to a shared pair of electrons

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diagmagnetism

Temporary magnetism provoked by an external magnetic field aligning paired electrons in a transition metal complex

dipole-dipole forces

The attraction between oppositely charged dipoles of two polar molecules

ductility

A metal's ability to be drawn into a wire

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electron delocalizatoin

The ability of a molecule to share electrons between multiple atoms due to aligned p-orbitals

electron domain

The number of bonding and non-bonding pairs of electrons

electronegativity

Relative measure of the attraction an atom has for a shared pair of electrons when covalently bonded to another atom

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ferromagnetism

Permanent magnetism due to parallel aligned unpaired electrons, exhibited in Fe, Ni, and Co

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hybridization

The mixing of bonding orbitals depending on the number of electron domains

hydrogen bonding

A dipole-dipole force that occurs between compounds with a hydrogen atom, and a lone pair present on one of nitrogen, oxygen, or fluorine

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hydrolysis reaction

A reaction that uses water to split a disaccharide into two monosaccharides

instantaneous dipole

A dipole created by having a high concentration of electrons in a certain area at any point in time. Found in London dispersion forces 

intermolecular forces

The forces between molecules

ionic bond

The electrostatic attraction between oppositely charged ions

Isoelectric

Atoms that have the same electron configuration 

Lewis structure

A visual representation of covalent compounds, showing all valence electrons as dots, lines or Xs

malleability

A metal's ability to bend

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metabolism

The sum of all chemical reactions taking place within an organism

metallic bond

The electrostatic attraction between a lattice of positive ions and delocalized electrons

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monomer

A small molecule

non-polar bond

A bond formed when there is an electronegativity difference of <0.5, leading to no poles being formed

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paramagneitsm

Temporary magnetism provoked by an external magnetic field aligning unpaired electrons in a transition metal complex

polar bond

A bond formed when there is an electronegativity difference of 0.5-1.8, leading to one atom pulling electrons more towards itself to create a negative pole on its side and a positive pole on the other atom

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Polyamides

Polymers formed when a diamine reacts with a dicarboxylic acid, releasing a water molecule for every amide link formed

polyatomic ion

Ions formed from more than one element, often when an acid loses one of more hydrogen ions

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Polyesters

Polymers formed when a dialcohol reacts with a dicarboxylic acid, releasing a water molecule for every ester link formed

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radical

Atom with a lone electron, making it highly reactive

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radical species

Atoms with a lone electron, making them highly reactive

resonance hybrids

A molecule that has more than one correct lewis structure

resultant polarity

The directional sum of polarity when a molecule has multiple polar bonds

valence shell

Outermost energy level of an atom 

VSEPR theory

Valence shell electron pair repulsion theory. Allows us to determine the correct 3D shape of a covalent compound

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π-bond

The sideways overlap of two p-orbitals resulting in an electron density lying above and below the internuclear axis

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σ-bond

The direct head-on overlap of two orbitals resulting in an electron density lying along the internuclear axis that forms a single bond

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