IB Chemistry Sub-topic S3.2 Definitions

This page contains our IB Chemistry definitions for sub-topic S3.2. By learning each one of these definitions, you will fully cover the content for IB Chemistry 'Further functional groups'.
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chiral carbon

A carbon bonded to four different groups

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cis-isomerism

Attached groups are the same on the same side of the bond plane

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cis-trans isomerism

Isomerism that only occurs with bond rotation restriction and communicates symmetry around the bond plane based on group identity

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configurational isomers

Molecules with different arrangements that require bond breaking and reforming to align

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conformational isomers

Molecules with different spatial arrangements that can be aligned by bond rotation

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diastereomer

Optical isomers that are not mirror images of each other

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E-isomerism

The groups with the highest atomic numbers are on opposite sides of the bond plane

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E/Z isomerism

Isomerism that only occurs with bond rotation restriction and communicates symmetry around the bond plane based on atomic number

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enantiomers

Optical isomers that are mirror images of each other

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fingerprint region

A unique pattern of absorption in the wavenumber region of 1400-400 cm-1

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H NMR

A method that provides information about the environment of hydrogen atoms

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hydrogen environment

The atom that the hydrogen is attached to and atoms bonded to that atom

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index of hydrogen deficiency (IHD)

A measure of saturation of an organic molecule

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infrared spectroscopy

A method that shines infrared light on molecules and measure absorption

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mass spectrometry

A method that vaporizes and ionizes a sample molecule, and then deflects its into different fragments with magnetic field

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optical isomerism

Isomerism where two molecules have the same molecular and structural formuals but are not super-imposable

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polarimeter

A device that detects the optical activity of enantiomers

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racemic mixture

A mixture with equal amounts of enantiomers, which is optically inactive

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Spin-spin coupling

Produces the splitting pattern on H-NMR due to the influence of Hydrogen nuclei on other neighbouring Hydrogen nuclei

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stereoisomers

Molecules with the same structural formula but different spatial arrangements

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trans-isomerism

Attached groups are the same on opposite sides of the bond plane

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X-ray crystallography

A method that shines X-rays on bonds and uses a sensor to detect the diffraction of the X-rays to measure bond length

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Z-isomerism

The groups with the highest atomic numbers are on the same side of the bond plane

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